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Ref. No. [UMCES] CBL 2015-014

ACT VS15-07

31

Moss Landing Marine Laboratories Field Deployment Site

A month-long moored field test was conducted at the Moss Landing Marine Laboratories

from August 26 to September 22, 2013. The deployment site was located at 36.80°N, 121.79°W,

in the Small Boat Facilities area of Moss Landing Harbor (Photo 2). This secure deployment site

was located in the Harbor on the junction of the northern tributary of the Salinas River and

Elkhorn Slough National Estuarine Reserve on the central coast of California. Instrumentation

was deployed off a floating dock in waters with a tidal range of 2 meters and a maximum depth

below the dock of 4 meters.

Photo 2.

Aerial view of MLML Harbor (left) and dockside mooring deployment (right).

Time series results of ambient conditions for tidal height, temperature, and salinity are

given in figure 13. Temperature ranged from 14.9 to 18.6 and salinity from 30.7 to 33.7 over

the duration of the field test. The bottom panel displays the maximum difference recorded

between all reference thermistors (RBR solo and SBE 26) mounted at the same depth and

different locations across the mooring rack. The average temperature difference observed was

0.11

o

C with a maximum of 0.8

o

C. The difference between the test instruments instantaneous

temperature reading and the final reference temperature will contribute to the variability and

offset to the calculated ambient reference pH. It is not possible to quantify the exact difference

between the averaged reference temperature and that measured by the test instrument, but a

difference of 1

o

C would amount to an approximate offset of 0.015 pH units at ambient

conditions. Additional differences resulting from variation in the actual chemistry of the water

across this space may exist but will be minimized because the sampling bottle integrates across

the mooring space.

The EXO sonde deployed for this field test contained two separate pH probes and each

probe is reported on separately and designated as EXO-pH1 and EXO-pH2 as defined by the

sensor location ID. Both probes operated continuously over the 28 days of the deployment and

each generated 2575 observations at 15 minute intervals. Time series results of the EXO-pH1

and corresponding reference pH results are given in figure 14. Ambient pH measured by the

EXO-pH1 ranged from 7.96 to 8.27, compared to the range captured by reference samples of

7.933 to 8.077. The bottom panel presents the time series of the difference between instrument

and reference pH measurements for each matched pair (n=84 observations). The average and