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Ref. No. [UMCES] CBL 2015-014

ACT VS15-07

19

Figure 3.

Time series of the Xylem EXO-pH1 test instrument pH results along with the dye reference pH

results for the complete ten week lab test. Results include nine rapid pH transition tests conducted at each

temperature and salinity condition. Detailed plots of each transition test are provided in Appendix I.

The EXO-pH2 also operated continuously throughout the entire lab test and generated

6286 pH measurements at 15 minute intervals (Fig. 4). The total range of pH measured by the

EXO-pH2 was nearly identical at 7.03 to 8.49, and again in close agreement with the range of the

reference pH of 6.943 to 8.502. The EXO-pH2 measurements tracked reference pH similarly

among all water sources and temperature ranges, and consistently responded to the rapid pH

shifts from acid/base additions. The average difference between the EXO-pH2 and reference pH

was 0.04 ±0.10 (N=266), with a total range of -0.31 to 0.19. Initial instrument measurements

conducted with the second seawater trial on the tenth week exhibited a slightly higher offset

(mean difference = 0.17 ±0.003; N=7) compared to measurements from the first week (mean

difference = 0.08 ± 0.007; N=28) (data not shown).