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Ref. No. [UMCES] CBL 2016-010

ACT VS16-01

5

third sample, the rosette was quickly profiled into the hypolimnion were samples were collected

immediately upon arrival and then each minute for the next 6 minutes. The second trial was performed

in the reverse direction. Note for Muskegon Lake cast 1 was aborted due to bottle misfires and

repeated as cast 3. In Muskegon Lake, the Aro-USB exhibited a negative bias in the colder, low DO

hypolimnion and a positive bias in the warm, high DO surface. Sensor equilibration time was slightly

greater going from surface to hypolimnetic conditions. The range in measurement differences between

instrument and reference was -0.42 to 0.34 mg/L for cast 2 and -0.75 to 0.27 mg/L for cast 3.

In Lake Michigan, the Aro-USB exhibited a positive bias in both portions of the water column

but the magnitude was higher in the cold high DO hypolimnion. Sensor equilibration time was similar

between both trials, whether equilibrated at surface or depth. The range in measurement differences

between instrument and reference was -0.16 to 0.53 mg/L for cast 1 and 0.18 to 0.50 mg/L for cast 2.

BACKGROUND AND OBJECTIVES

Instrument performance verification is necessary so that effective existing technologies can be

recognized and promising new technologies can be made available to support coastal science, resource

management and ocean observing systems. To this end, the NOAA-funded Alliance for Coastal

Technologies (ACT) serves as an unbiased, third party testbed for evaluating sensors and sensor

platforms for use in coastal environments. ACT also serves as a comprehensive data and information

clearinghouse on coastal technologies and a forum for capacity building through workshops on specific

technology topics (visit

www.act-us.info

).

As part of our service to the coastal community, ACT conducted a performance verification of

commercially available, in situ dissolved oxygen (DO) sensors through the evaluation of objective and

quality assured data. The goal of ACT’s evaluation program is to provide technology users with an

independent and credible assessment of instrument performance in a variety of environments and

applications. To this end, the data and information on performance characteristics were focused on the

types of information users most need.

The fundamental objectives of this Performance Verification were to: (1) highlight the

potential capabilities of particular in situ DO sensors by demonstrating their utility in a range of coastal

environments; (2) verify the claims of manufacturers on the performance characteristics of

commercially available DO sensors when tested in a controlled laboratory setting, and (3) verify

performance characteristics of commercially available DO sensors when applied in real world

applications in a diverse range of coastal environments.

INSTRUMENT TECHNOLOGY TESTED

For this performance evaluation both the JFE Advantech RINKO AroUSB and AroW-USB

were tested during all laboratory trials. The AroUSB was additionally evaluated in the profiling field

test in Michigan, and the AroW-USB was evaluated in the three field deployment tests at Michigan,

Maryland, and Hawaii. JFE Advantech RINKO AroUSB and AroW-USB are high-accuracy and

high-resolution optical dissolved oxygen (DO) sensors based on the phosphorescence principle. The

sensors are coated with photo-stimulable phosphor (PSP) on the outside of the pressure-resistant

acrylic optical window, measuring a phosphorescence quenching phase shift. The excitation blue LED

pulse generates a red phosphorescence pulse, which in turn has an inverse correlation with the oxygen

partial pressure in water (DO concentration). Since the method does not consume oxygen, there is no

need for stirring. The instruments offer a user friendly 2-point calibration that compensates the sensing