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Ref. No. [UMCES] CBL 2015-014

ACT VS15-07

41

A cross-plot of the matched observations of EXO-pH1 and reference pH is given in

figure 20. The linear regression was statistically significant (p<0.001, r

2

=0.88) with a slope of

1.08 and an intercept of -0.45.

Figure 20.

HIMB field response plot of EXO-pH1 (dark red circles) and the second deployed EXO

sonde pH (grey circles) compared to reference pH

Total

samples. Fine dotted line represents 1:1

correspondence, coarse dotted line represents correspondence predicted based on difference between

pH

NBS

and pH

Total

in seawater (pH

NBS

= pH

Total

+ 0.13).

Time series results of the EXO-pH2 and corresponding reference pH results are given in

figure 21. Ambient pH measured by the EXO-pH2 ranged from 7.79 to 8.22, compared to the

range measured from reference samples of 7.814 to 8.084. The bottom panel presents the time

series of the difference between instrument and reference pH measurements for each matched

pair (n=29 observations out of a possible 101 for the total deployment). The average and

standard deviation of the difference between EXO-pH2 and reference pH over the total